Exponential Quantum Mechanics

The class of unified theories that I’ve been studying for the last 14 years had a minor but annoying problem, but I was afraid to tackle it until this summer. And suddenly, it’s led me into a strange new world where I had to re-think quantum mechanics from the ground up.

Here’s the problem: In General Relativity, or even just Special Relativity plus the Einstein Equivalence Principle (that gravity and acceleration feel the same because they ARE the same), you get Gravitational Time Dilation. Einstein first worked this out in 1907, and got that the time dilation factor had to be Td = 1 + 𝚽/c² to first order. This can also be written Td = 1 + m𝚽/mc² = 1 + ∆E/mc²; here we emphasize that the last term can be written as a ratio of energies. 𝚽 is the gravitational potential, m𝚽 is the potential energy of a mass m at potential 𝚽, and mc² is the rest mass energy of the same mass.

But Einstein also noted that the linear formula couldn’t be exactly right. The reason is simple. Let’s say you and I run an experiment with synchronized start and stop, and you measure S₁ seconds on your clock, and I measure S₀ seconds on my clock. Then the time dilation I see you as having is Td(1<-0) = S₁ / S₀, and the time dilation you ascribe to me is Td(0<-1) = S₀ / S₁. It must always be the case that Td(1<-0) * Td(0<-1) = (S₁ / S₀) * (S₀ / S₁) = 1, exactly. But using the linear formula, we get Td(1<-0) = 1 + 𝚽/c² and Td(0<-1) = 1 – 𝚽/c², and so Td(1<-0) * Td(0<-1) = (1 + 𝚽/c²) * (1 – 𝚽/c²) = 1 – (𝚽/c²)². It’s not exactly 1.

Einstein wrote that the exact formula had to be Td = exp(𝚽/c²) = exp(m𝚽/mc²). This fixes the problem. This exponential dependence of time on energy is inescapable in relativity theory.

When we look at quantum mechanics, we see something similar. Wave functions that are higher in energy rotate their quantum phase faster, those that are lower in energy rotate their phase more slowly. And in fact if we use the total-energy which includes the rest mass energy (as Schrödinger himself did in his letter to Willy Wien), and consider E = h𝜈, we get the identical linear formula Td = 𝜈₁ / 𝜈₀ = ((mc² + ∆E)/h) / (mc²/h) = (mc² + ∆E) / mc² = 1 + ∆E/mc².

So, we would like to treat the phase frequency shifts in QM as being identical to the time dilations seen in GR, especially for the case of putting a gravitational potential into the Schrödinger equation. But while they are identical to first order, the linear equation in QM is exact; this appears forced by E = h𝜈 which implies 𝜈 = E/h. And the linear equation in GR is not quite correct; the exponential form is the exact one. So the two phenomena almost agree perfectly, but not quite.

This had been annoying me for years, but I didn’t know what to do about it. There’s no way to change the GR equation without breaking something. And hacking QM seemed insane; it’s one of the most successful theories in the history of science, and there were multiple papers published saying that any non-linear modification of it would have massive consequences, such as destroying causality. It seemed a far too difficult problem for me to tackle.

But early this year I came across another paper that said some nonlinearities might be tolerable. Without going into the details, I felt that this gave me a license to try. So I did. And it turned out to be much easier than I expected.

The normal SchrĂśdinger equation is:

iℏd/dt 𝛙 = Ĥ 𝛙

This gives the correct eigenfunctions (e.g. atomic orbitals), but the implied phase frequency is 4 orders of magnitude too low. We have to add in the rest mass energy to get the frequencies right:

iℏd/dt 𝛙 = (mc² + Ĥ) 𝛙

This “total energy” version of the SchrĂśdinger equation is what we want to match as closely as possible. To get an exponential time dependence, we could try an equation that had exp(Ĥ) in it, but that doesn’t work. The power series expansion gives:

exp(Ĥ) = 1 + Ĥ + Ĥ²/2! + Ĥ³/3! + …

and this doesn’t make dimensional sense, because the terms have dimensions of dimensionless (1), energy (Ĥ), energy squared (Ĥ²/2!), and so on; they can’t be added together. Taking a hint from the GR equation Td = exp(m𝚽/mc²), we can try normalizing by dividing by mc²:

exp(Ĥ/mc²) = 1 + Ĥ/mc² + Ĥ²/2!(mc²)² + Ĥ³/3!(mc²)Âł + …

This makes dimensional sense since all the terms are dimensionless. But it doesn’t quite match the SchrĂśdinger equation; we want the first two terms to be mc² + Ĥ. We can fix this by multiplying through by mc²:

mc²exp(Ĥ/mc²) = mc² + Ĥ + Ĥ²/2!mc² + Ĥ³/3!(mc²)² + …

which matches the standard (total energy) equation to first order in Ĥ. So our new quantum equation is:

iℏd/dt 𝛙 = mc²exp(Ĥ/mc²) 𝛙

or, defining a new operator X̂ ≡ mc²exp(Ĥ/mc²), simply

iℏd/dt 𝛙 = X̂ 𝛙

This defines a new version of quantum mechanics that I call Exponential Quantum Mechanics or XQM.

We now need to figure out what this breaks, and what it doesn’t. What I know so far:

  • X̂ is Hermitian. X̂† = mc²exp(Ĥ†/mc²) = mc²exp(Ĥ/mc²) ≡ X̂
  • Spatial eigenfunctions are unchanged. Any eigenfunction 𝛙n of Ĥ with eigenvalue En is also an eigenfunction of X̂ with eigenvalue mc²exp(En/mc²). This means that e.g. chemical bond lengths and angles are unchanged.
  • Frequency is now an exponential function of energy. This matches gravitational time dilation perfectly. But, it means we have to give up thinking that E = h𝜈 is universally true.

There’s a lot more work to do here, including trying to do the same thing with the Dirac equation. But so far, so good. I managed to hack the SchrĂśdinger equation to warp its time behavior without breaking much; in particular, all of chemistry is unaltered. Not bad for an amateur. 🙂

Switzerland day 42: Bern & Einstein

Bern was where Albert Einstein was working as a patent clerk during his “miracle year” of 1905. In 6 months, he published 4 papers any one of which should have been worth a Nobel prize:

  • Photoelectric effect (submitted March 18, published June 9)
  • Brownian Motion (submitted May 11, published June 19)
  • Special Relativity (submitted June 30, published September 26)
  • Energy = Mass (submitted September 27, published November 21)

It’s probably the most productive year any scientist has ever had. None of the math was terribly hard, but each paper revolutionized an entire subject by looking at it differently.

September 30th: First target of the day was the Einstein Museum.

Hanging with my BFF

I got off to a rocky start in the museum, which restated a very wrong but perniciously widespread misconception.

This is wrong because (1) matter/mass/energy all bend space-time (not just space), and (2) time is always bent at least as much as space. Around the Earth, for slow-moving objects, gravity is more than 99.9999% due to bending of time, and less than 0.0001% due to bending of space. For extremely fast-moving objects it get closer to 50-50. So simplifying to “matter bends time” is OK and sometimes approximately correct, but simplifying to “matter bends space” is always wrong. Yet everyone does it. Jim Al-Khalili. Stephen Hawking.

Other than that, the physics was pretty good. However, a significant chunk of the exhibit was devoted to the rise of the Nazis and the development and use of nuclear weapons. I wasn’t expecting it to be so depressing.

Some random buildings in Bern:

We had lunch at the Äss Bar, a discount restaurant that gets 1-day-old bread from nearby bakeries and makes cheap sandwiches from it.

It’s pronounced “Ess”.

A famous clock tower was right on our way, so we waited for it to strike, but it was underwhelming. A few figures to the right of the red dial moved.

Farther down the same street was our second goal for the day: Kramgasse No. 49, the “Einsteinhaus”, the apartment where Einstein lived in 1903-5.

If you lean out Einstein’s window and look left, you can see the clock tower a half a block away. The theory of relativity is based on the behavior of “clocks” and “rulers”; I think I know what inspired the clock part. 🙂

Then we walked around town a bit.

Finally we had to head out for our drive to the Swiss Alps. They became obvious long before we reached them.